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Making alkenes: the Wittig reaction

Burning blue

For most people pyrotechnics provide entertainment, but for a select few the production of fireworks is a passion and a matter of pride. Display fireworks have small capsules containing a mixture of compounds that burst apart and burn brightly like coloured stars. Formulating colour-emitting pyrotechnic compositions requires understanding of many chemical concepts, from quantum theory to thermodynamics. Pyrotechnicians strive to create new and exciting effects, but they are also on a quest to produce the perfect blue flame.

Copper compounds are used to produce blue flames. However, when copper compounds are burnt in a bunsen burner flame they emit light in the green region of the spectrum (see Figure 1 and CHEMISTRY REVIEW, Vol. 17, No. 1, p. 34). So where is the blue colour coming from?

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Making alkenes: the Wittig reaction

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