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IN PICTURES

The chemistry of pearls

Hannah Cooke looks at the chemistry of pearls as part of the commemoration of CHEMISTRY REVIEW’s 30th (pearl) anniversary

Pearls are organic gems formed in the soft tissue of giant clams, pearl oysters and other molluscs. When a microscopic object, such as a parasite or shell fragment, gets trapped in the soft tissue of the mollusc, it irritates the tissue’s epithelial cells. In response, the mollusc envelopes the irritant in a sac and a crystalline substance called nacre is secreted, which coats the irritant. Over time, a pearl is formed (Figure 1).

Nacre, also known as mother of pearl, is composed of the mineral aragonite, a form of calcium carbonate (CaCO3, see Figure 2 and CHEMISTRY REVIEW, Vol. 20, No. 3, pp. 8–11). The combination of inorganic aragonite in an organic protein matrix (namely conchiolin) means that nacre is a composite material.

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